IR spectra of porous silicon based nanocomposites
Paper #3313 received 30 Jan 2019; revised manuscript received 3 Apr 2019; accepted for publication 1 May 2019; published online 27 May 2019.
The article is devoted to the problem of using porous silicon
(por-Si) as a biomaterial. IR spectroscopy was used to study the composition of por-Si samples and nanocomposites: por-Si with hydroxyapatite, promising as a biomaterial for osteoplasty and por-Si with glucose (for biosensor). The studies were carried out on the FSM 2201 Fourier spectrometer using the diffuse reflection prefix and Perkin Elmer Spectrum 100 using the total internal reflection violation prefix. A comparative analysis of the results shows a noticeable difference between the IR spectra of nanocomposites and the IR spectrum of the original por-Si and allows to identify the substance in the pores.
1. M. Simion, I. Kleps, T. Neghina, A. Angelescu, M. Miu, A. Bragaru, M. Danila, E. Condac, M. Costache, and L. Savu, “Nanoporous silicon matrix used as biomaterial,” Journal of Alloys and Compounds 434–435, 830–832 (2007). Crossref
2. O. I. Ksenofontova, A. V. Vasin, V. V. Egorov, , A. V. Bobyl', F. Y. Soldatenkov, E. I. Terukov, V. P. Ulin, N. V. Ulin, and O. I. Kiselev, “Porous silicon and its applications in biology and medicine,” Technical Physics59(1), 66–77 (2014). Crossref
3. N. V. Latuhina, G. A. Pisarenko, A. V. Volkov, and V. A. Kitaeva, “Fotochuvstvitel’naya matrica na osnove poristogo mikrokristallicheskogo kremniya,” Vestnik Samarskogo gos. universiteta. Estestvennonauchnaya seriya 5(86), 115–121 (2011) [in Russian].
4. C. Lee, H. Kim, C. Hong, M. Kim, S. S. Hong, D. H. Lee, and W. I. Lee, “Porous silicon as an agent for cancer thermotherapy based on near-infrared light irradiation,” Journal of Materials Chemistry 18(40), 4790–4795 (2008). Crossref
5. L. A. Osminkina, K. P. Tamarov, A. P. Sviridov, R. A. Galkin, M. B. Gongalsky, V. V. Solovyev, A. A. Kudryavtsev, and V. Y. Timoshenko, “Photoluminescent biocompatible silicon nanoparticles for cancer theranostic applications,” Journal of Biophotonics 5(7), 529–535 (2012). Crossref
6. L. Pramatarova, E. Pecheva, D. Dimova-Malinovska, R. Pramatarova, U. Bismayerc, T. Petrov, and N. Minkovski, “Porous silicon as a substrate for hydroxyapatite growth,” Vacuum 76(2–3), 135–138 (2004). Crossref
7. J. L. Coffer, M. A. Whitehead, D. K. Nagesha, P. Mukherjee, G. Akkaraju, M. Totolici, R. S. Saffie, and L. T. Canham, “Porous silicon-based scaffolds for tissue engineering and other biomedical applications,” Physica Status Solidi (A) 202(8), 1451–1455 (2005). Crossref
8. T. J. Barnes, L. J. Karyn, and C. A. Prestidge, “Recent advances in porous silicon technology for drug delivery,” Therapeutic Delivery 4(7), 811–823 (2013). Crossref
9. Y. M. Spivak, N. R. Nigmadzyanova, “Poluchenie poristogo kremhiya dlya primeneniya v adresnoy dostavke lekarctv,” Molodoy ucheniy 10, 208–212 (2014) [in Russian].
10. S. Dhanekar, S. Jain, “Porous silicon biosensor: Current status,” Biosensors and Bioelectronics 41, 54–64 (2013). Crossref
11. B. Gupta, Y. Zhu, B. Guan, P. J. Reece, and J. Gooding, “Functionalised porous silicon as a biosensor: emphasis on monitoring cells in vivo and in vitro,” The Analyst 138(13), 3593–3615 (2013). Crossref
12. D. Fan, G. R. Akkaraju, E. F. Couch, L. T. Canham, and J. L. Coffer, “The role of nanostructured mesoporous silicon in discriminating in vitro calcification for electrospun composite tissue engineering scaffolds,” Nanoscale 3(2), 354–61 (2011). Crossref
13. M. A. Whitehead, D. Fan, G. R. Akkaraju, L. T. Canham, and J. L. Coffer, “Accelerated calcification in electrically conductive polymer composites comprised of poly(epsilon-caprolactone), polyaniline, and bioactive mesoporous silicon,” Journal of Biomedical Materials Research Part A 83A(1), 225–234 (2007). Crossref
14. E. M. Carlisle, “Silicon as a trace nutrient,” Science of The Total Environment 73(1–2), 95–106 (1988). Crossref
15. E. V. Berlova, A. S. Domchenkova, V. A. Zhukova, and N. V. Latuhin, “Nanokomposity poristogo kremniya s gidroksiapapitom dlyamedicinskih prilozheniy,” Sbornic materialov V Vserossiyskoy konferencii po nanomaterialam “Nano 2013”, 382 (2013) [in Russian].
16. S. Zairi, C. Martelet, N. Jaffrezic-Renault, R. M'gaïeth, H. Maâref, and R. Lamartine, “Porous silicon a transducer material for a high-sensitive (bio)chemical sensor: effect of a porosity, pores morphologies and a large surface area on a sensitivity,” Thin Solid Films 383(1–2), 325–327 (2001). Crossref
17. Y. A. Vashpanov, I. P. Konup, V. A. Smyntyna, and V. A. Ivanica, “Vliyanie adsorbcii biologicheskih molecul na elektronnye parametry poristogo kremniya,” Vestnic Odeskogo nacional’nogo Universiteta 11(7), 39–46 (2006) [in Russian].
18. N. Y. Arbatskaya, “Sovremennye pribory dlya samokontrolya urovnya sahara krovi,” Lechashchiy vrach 5, 46–53 (2005).
19. “Nanotehnologii v medicine. Realnost ili poka tolko mif?” Nano News Net [in Russian].
20. N. A. Bazaev, Y. P. Masloboev, and S. V. Seliszhev, “Opticheskie metody neinvazivnogo opredeleniya urovnya glukozy v krovi,” Medicinskaya tehnika 6(270), 29–33 (2011).
21. A. L. Smeth, Applied IR spectroscopy. Fundamentals, techniques and analytical problem solving, Wiley, New York (1979).
22. L. A. Kazicyna, N. B. Kupletskaya, Primenenie UF-, IK- I YaMR-spectroscopii v organicheskoy himii, Vysshaya shkola, Moscow (1971) [in Russian].
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